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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Allyl acetate ： ウィキペディア英語版 Allyl acetate |Section2= |Section7= }} Allyl acetate is an organic compound with formula C3H5OC(O)CH3. This colourless liquid is a precursor to especially allyl alcohol, which is a useful industrial intermediate. It is the acetate ester of allyl alcohol. ==Preparation== Allyl acetate is produced industrially by the gas phase reaction of propene in the presence of acetic acid using a palladium catalyst: :C3H6 + CH3COOH + ½ O2 → CH2=CHCH2OCOCH3 + H2O This method is advantageous because propene is inexpensive and "green." Allyl alcohol is also produced primarily from allyl chloride, but production via the hydrolysis of allyl acetate route avoids the use of chlorine, and so is increasing in use. Vinyl acetate is produced similarly, using ethylene in place of propene. These reactions are examples of acetoxylation. The palladium center is then re-oxidized by the O2 present. The mechanism for the acetoxylation follows a similar pathway, with propene forming a π-allyl bond on the palladium. : 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Allyl acetate」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.